5.11C - Calculating percentage yield

5.11C - Calculating percentage yield

Percentage yield compares the product actually obtained with the calculated maximum. You will choose the correct masses, make their units consistent and calculate or check a percentage yield.

Actual and theoretical yield

A yield is the amount of product formed in a reaction. Percentage yield needs two product amounts: the amount actually obtained and the calculated amount that could be obtained.

Actual yield

The actual yield is the mass or amount of product obtained from the reaction or experiment.

The theoretical value is different because it comes from calculation, not from collecting and measuring the product.

Theoretical yield

The theoretical yield is the calculated maximum mass or amount of product that could be formed from the given reactants.

Both values must refer to the same product. If a question is about copper sulfate crystals, the actual yield and theoretical yield must both be for copper sulfate crystals, not for a reactant used to make them.

Most GCSE questions give both values directly. A previous part of a longer question may calculate the theoretical yield from a balanced equation, but this lesson focuses on using the actual yield and theoretical yield once they are known.

The percentage yield formula

Percentage yield is a comparison:

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what was obtained / what could be obtained

Then multiply by 100 to convert the fraction into a percentage.

Percentage yield

percentage yield=actual yieldtheoretical yield×100\text{percentage yield} = \frac{\text{actual yield}}{\text{theoretical yield}} \times 100

The answer has the unit %. The actual yield and theoretical yield must use the same unit before you divide. For example, dividing g by g leaves no mass unit; multiplying by 100 gives a percentage.

A clear layout helps you check your method and can earn partial credit if you make an arithmetic slip. The number of written lines is not the number of marks. For a direct percentage-yield calculation, a correct final answer can earn full marks without showing each line; follow any explicit instruction to explain or show a particular result. You can organise your working as follows:

  1. Write the formula.
  2. Substitute the actual yield and theoretical yield.
  3. Do the division and multiply by 100.
  4. Give the answer with %, and round at the end to the requested precision, or to a sensible precision for the data.

Worked example: a reaction has a theoretical yield of 4.80 g. The actual yield is 3.84 g. Calculate the percentage yield.

Formula:

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percentage yield = actual yield / theoretical yield x 100

Substitution:

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percentage yield = 3.84 / 4.80 x 100

Working:

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3.84 / 4.80 = 0.800
0.800 x 100 = 80.0

Answer:

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percentage yield = 80.0%

Choosing the correct values

The numerator is the actual yield: the product mass obtained. The denominator is the theoretical yield: the product mass calculated or given as the maximum possible amount.

Information in the questionRole in the formula
"mass obtained", "mass collected", "actual yield"actual yield
"calculated mass", "maximum mass", "theoretical yield"theoretical yield
mass of reactant usednot used directly in this formula
mass of product lost or left behindnot used unless the question asks for actual yield first

For example, if a calculation predicts 10.0 g of zinc sulfate and 7.35 g is obtained, use 7.35/10.0×100=73.5%7.35 / 10.0 \times 100 = 73.5\%.

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