6.4.4(a)-(f) - Mass-energy, binding energy and nuclear reactions

6.4.4(a)-(f) - Mass-energy, binding energy and nuclear reactions

Nuclear reactions are a place where a very small change in rest mass can correspond to a large amount of energy. In this lesson you will use Einstein's mass-energy equation, connect it to particle-antiparticle pairs, and calculate binding energy from masses. You will also learn how the binding-energy-per-nucleon curve predicts whether a supplied nuclear reaction can release energy.

Mass-energy accounting

The key idea is not that mass simply disappears. In nuclear and particle reactions, rest mass can be converted into other forms of energy, such as kinetic energy of products or photon energy. The reverse can also happen: energy can be absorbed to create extra rest mass.

Einstein's mass-energy equation

ΔE=Δmc2\Delta E = \Delta m c^2

Here c=3.00×108 m s−1c = 3.00 \times 10^8\ \text{m s}^{-1}. The OCR data booklet gives this relationship, but you need to choose the correct mass difference and use SI units unless the question clearly gives another route.

For an energy-releasing reaction,

Δm=mreactants−mproducts\Delta m = m_{\text{reactants}} - m_{\text{products}}

so Δm\Delta m is positive when the products have less rest mass than the reactants. The energy released is then Δmc2\Delta m c^2. If the products have greater rest mass, the reaction has absorbed energy instead.

[DIAGRAM: asset_name: 6.4.4(a)-(f) - Mass-energy, binding energy and nuclear reactions - diagram 1; asset_slug: 6_04_4a_mass_energy_binding_energy_and_nuclear_reactions__diagram_01; recommended_method: drawn_physics; description: Distinct reactant/product rest masses with positive mass decrease supplying kinetic/photon energy; reverse condition stated.; caption: A decrease in total rest mass supplies the kinetic and photon energy released by a nuclear reaction.]
A decrease in total rest mass supplies the kinetic and photon energy released by a nuclear reaction.

Worked example: a supplied nuclear reaction has products whose total rest mass is 4.20×10−29 kg4.20 \times 10^{-29}\ \text{kg} less than the total rest mass of the reactants. Calculate the energy released.

ΔE=Δmc2\Delta E = \Delta m c^2 ΔE=(4.20×10−29)(3.00×108)2\Delta E = (4.20 \times 10^{-29})(3.00 \times 10^8)^2 ΔE=3.78×10−12 J\Delta E = 3.78 \times 10^{-12}\ \text{J}

Since 1 MeV=1.60×10−13 J1\ \text{MeV} = 1.60 \times 10^{-13}\ \text{J},

ΔE=3.78×10−121.60×10−13=23.6 MeV\Delta E = \frac{3.78 \times 10^{-12}}{1.60 \times 10^{-13}} = 23.6\ \text{MeV}

The joule is the SI answer. The MeV value is often a more convenient nuclear-scale value.

Pairs and photons

A particle and its antiparticle have the same rest mass. Charged partners such as an electron and a positron have opposite electric charges; neutral partners both have zero net electric charge. When a particle-antiparticle pair annihilates, their rest mass energy is converted into photon energy. For an electron and a positron initially with negligible kinetic energy, the total energy available is

2mec22m_e c^2

where me=9.11×10−31 kgm_e = 9.11 \times 10^{-31}\ \text{kg}.

Two photons are usually emitted in opposite directions. This is not just a tidy diagram convention: it helps conserve momentum when the electron and positron were initially close to rest.

Pair creation is the reverse process. A photon with sufficient energy can create a particle-antiparticle pair, but momentum must still be conserved, so this occurs near another body such as a nucleus. For electron-positron pair creation, the minimum photon energy is the rest energy of both particles:

Eγ,min⁡=2mec2E_{\gamma,\min} = 2m_e c^2

Any photon energy above this minimum can appear as kinetic energy of the created particles.

[DIAGRAM: asset_name: 6.4.4(a)-(f) - Mass-energy, binding energy and nuclear reactions - diagram 2; asset_slug: 6_04_4a_mass_energy_binding_energy_and_nuclear_reactions__diagram_02; recommended_method: drawn_physics; description: Opposite equal-energy annihilation photons; pair creation near a separately drawn recoil nucleus with threshold condition.; caption: Pair annihilation at rest produces opposite photons. Pair creation near a nucleus produces an electron and positron.]
Pair annihilation at rest produces opposite photons. Pair creation near a nucleus produces an electron and positron.

Worked example: find the minimum photon energy needed to create an electron-positron pair.

Eγ,min⁡=2mec2E_{\gamma,\min} = 2m_e c^2 Eγ,min⁡=2(9.11×10−31)(3.00×108)2E_{\gamma,\min} = 2(9.11 \times 10^{-31})(3.00 \times 10^8)^2 Eγ,min⁡=1.64×10−13 JE_{\gamma,\min} = 1.64 \times 10^{-13}\ \text{J}

In electronvolts,

Eγ,min⁡=1.64×10−131.60×10−19=1.02×106 eV=1.02 MeVE_{\gamma,\min} = \frac{1.64 \times 10^{-13}}{1.60 \times 10^{-19}} = 1.02 \times 10^6\ \text{eV} = 1.02\ \text{MeV}

For annihilation of a stationary electron-positron pair into two equal photons, each photon has half the total energy: mec2=8.20×10−14 Jm_e c^2 = 8.20 \times 10^{-14}\ \text{J}. If asked for the wavelength of each photon, use E=hf=hc/λE = hf = hc/\lambda, so λ=hc/E\lambda = hc/E.

Mass defect and binding energy

A nucleus has less mass than the total mass of the separated protons and neutrons that make it up. That difference is the mass defect.

Mass defect

The mass defect of a nucleus is the difference between the total mass of its separated nucleons and the mass of the nucleus.

For a nucleus with proton number ZZ and nucleon number AA, the number of neutrons is A−ZA - Z. If nuclear masses are being used,

Δm=Zmp+(A−Z)mn−mnucleus\Delta m = Zm_p + (A-Z)m_n - m_{\text{nucleus}}

where mpm_p is the proton mass and mnm_n is the neutron mass.

The mass defect corresponds to binding energy.

Binding energy

The binding energy of a nucleus is the minimum energy needed to separate the nucleus completely into its individual protons and neutrons, with the separated nucleons far apart. The same amount of energy is released when the nucleus is formed from those separated nucleons.

Binding energy per nucleon

Binding energy per nucleon is the total binding energy of a nucleus divided by its nucleon number AA.

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