1.9 - Isotopes
Isotopes let atoms belong to the same element while having different masses. Learn the two conditions for an isotope pair and use particle counts to identify one.
Same element, different neutron counts
Isotopes
Atoms of the same element with the same number of protons but different numbers of neutrons in their nuclei.
Proton number fixes the element’s identity. Neutrons contribute to mass number but do not change that identity. Therefore different isotopes of one element have different mass numbers.
For example, chlorine-35 and chlorine-37 each have 17 protons. Their neutron counts are 35 − 17 = 18 and 37 − 17 = 20. They are the same element but different isotopes.
Two separate atoms with identical proton and neutron counts are atoms of the same isotope. Being two separate atoms is not enough to make them different isotopes.
Checking both conditions
First compare protons. If these differ, the atoms are different elements. If protons match, compare neutrons: different neutron counts mean different isotopes.
Worked comparison
| Atom | Protons | Neutrons |
|---|---|---|
| A | 6 | 6 |
| B | 6 | 8 |
| C | 7 | 7 |
A and B are different isotopes of the same element: both have 6 protons, but they have 6 and 8 neutrons. B and C both have mass number 14, but their proton numbers differ, so they are different elements.