1.22 - Understanding ions

1.22 - Understanding ions

Ions can be charged single atoms or charged groups of atoms. You will learn how to read their symbols and distinguish them from neutral atoms and molecules.

Recognising a charged particle

Ion

An ion is an atom or group of atoms with an overall positive or negative charge.

The charge is written at the upper right of the symbol. Na+Na^+ is a positive sodium ion; ClCl^- is a negative chloride ion. A sign without a number means a charge of one. Mg2+Mg^{2+} has a charge of two plus.

A neutral atom, such as NeNe, has no overall charge. A molecule can also be neutral: O2O_2 contains two oxygen atoms, but the subscript 2 is an atom count, not a charge. It is not an ion.

When the whole group is charged

In a group ion, several atoms together have one overall charge. The sulfate ion, SO42SO_4^{2-}, contains one sulfur atom and four oxygen atoms; the whole group has a charge of two minus. The hydroxide ion, OHOH^-, contains oxygen and hydrogen with a charge of one minus for the whole group.

The subscript counts atoms within the group. The superscript gives the charge on the whole ion. Thus SO42SO_4^{2-} is one ion containing five atoms, not five separate ions. Saying only “a charged atom” leaves out this kind of ion.