1.24 - How ions form in ionic compounds

1.24 - How ions form in ionic compounds

The outer-shell electrons of Groups 1, 2, 6 and 7 help predict the ions formed in their ionic compounds. You will connect group number, electron transfer and charge, including cases where more than one atom supplies or receives electrons.

Group number and ion charge

When a neutral atom loses electrons it becomes positive; when it gains electrons it becomes negative. Protons remain in the nucleus. For the Group 1 and 2 metals and Group 6 and 7 non-metals considered here, the usual simple ions have full outer electron shells.

GroupOuter-shell electronsChange per atomUsual ion chargeExample
1 metals1lose 1 electron1+Na+Na^+
2 metals2lose 2 electrons2+Mg2+Mg^{2+}
6 non-metals6gain 2 electrons2−O2O^{2-}
7 non-metals7gain 1 electron1−ClCl^-

For example, sodium changes from 2,8,1 to 2,8, while chlorine changes from 2,8,7 to 2,8,8. This is a pattern for the specified groups in these compounds, not a rule for every element.

Accounting for every transferred electron

In these metal–non-metal compounds, electrons lost by the metal atoms are gained by the non-metal atoms. The resulting opposite charges attract electrostatically.

Magnesium oxide: one magnesium atom loses two electrons and forms Mg2+Mg^{2+}. One oxygen atom gains both electrons and forms O2O^{2-}. The two electrons lost equal the two gained.

Calcium fluoride: one calcium atom loses two electrons and forms Ca2+Ca^{2+}. Each fluorine atom gains only one electron, so two fluorine atoms receive one electron each and form two FF^- ions. Do not turn one fluorine atom into F2F^{2-} to make the numbers fit.

When two metal atoms are needed

Lithium oxide: each lithium atom loses one electron, while one oxygen atom gains two. Two lithium atoms therefore supply one electron each to one oxygen atom. The products are two Li+Li^+ ions for each O2O^{2-} ion.

Explain ion formation by naming the number and direction of transferred electrons and the charges produced. “The atoms want to be stable” does not describe these changes. A full outer shell helps describe the resulting electronic arrangement, but it does not replace the electron-transfer account.