1.10 - Counting protons, neutrons and electrons

1.10 - Counting protons, neutrons and electrons

Use atomic number and mass number to calculate protons, neutrons and electrons in neutral atoms. Then check a set of particle counts for mistakes.

Choose the right relationship

Atomic number gives the number of protons. Mass number counts protons and neutrons together, so subtracting protons from that total leaves the neutron count.

Particle counts in a neutral atom

protons=atomic number\text{protons}=\text{atomic number} neutrons=mass numberatomic number\text{neutrons}=\text{mass number}-\text{atomic number} electrons=protons\text{electrons}=\text{protons}

The electron rule applies because an atom is neutral: equal numbers of positive protons and negative electrons balance its charge. For an ion, which has a net charge, the electron count is different. Here all particles described as atoms are neutral.

Mass number is a count of nucleons, not the decimal relative atomic mass on a periodic table. Do not substitute a relative atomic mass into the neutron calculation.

From two numbers to three counts

Worked example: An atom has atomic number 7 and mass number 15.

  1. Protons = 7.
  2. Neutrons = 15 − 7 = 8.
  3. Electrons = 7, because the atom is neutral.

Check: 7 protons + 8 neutrons = mass number 15; 7 electrons balance the 7 protons. Counts do not need a unit.

Checking the result

Check particle counts against both pieces of information. Protons must equal the atomic number; protons plus neutrons must equal the mass number; electrons must equal protons for a neutral atom.

An isotope change affects neutrons, so two isotopes of one element can have different mass numbers but the same proton and electron counts.