1.25 - Naming compounds: -ide and -ate
The endings -ide and -ate give clues about the elements in a compound. You will use familiar ionic compound names to interpret these clues and recognise why oxygen alone does not determine the ending.
The -ide ending
For many ionic compounds, the first word names the positive ion, often a metal. The second word names the negative ion. In a compound made from two elements, the non-metal name commonly changes to end in -ide.
| Elements | Compound name |
|---|---|
| sodium and chlorine | sodium chloride |
| magnesium and oxygen | magnesium oxide |
| lithium and bromine | lithium bromide |
| calcium and sulfur | calcium sulfide |
Chlorine is the element name; chloride is its negative ion name. Oxide contains oxygen, so an -ide ending does not mean that oxygen is absent.
The -ate ending
Names such as carbonate, nitrate and sulfate identify oxygen-containing negative group ions. The group contains oxygen together with another element.
| Compound | Elements present | Negative group contains |
|---|---|---|
| calcium carbonate | calcium, carbon, oxygen | carbon and oxygen |
| potassium nitrate | potassium, nitrogen, oxygen | nitrogen and oxygen |
| magnesium sulfate | magnesium, sulfur, oxygen | sulfur and oxygen |
Compare magnesium sulfide with magnesium sulfate. Sulfide contains sulfur without oxygen; sulfate contains sulfur and oxygen in the group ion. The compounds therefore contain different elements despite their similar names. The ending is a clue to the named ion, not enough information by itself to deduce the complete compound formula.
Using the clues carefully
Worked comparison: sodium chloride contains sodium and chlorine only; chlorine is named chloride in the compound. Sodium carbonate contains sodium, carbon and oxygen because carbonate is an oxygen-containing group ion.
Do not reverse the -ate clue into “every ion containing oxygen ends in -ate”. Hydroxide, , contains oxygen and hydrogen but ends in -ide. Learn common names accurately: hydroxide, nitrate, carbonate and sulfate.