1.25 - Naming compounds: -ide and -ate

1.25 - Naming compounds: -ide and -ate

The endings -ide and -ate give clues about the elements in a compound. You will use familiar ionic compound names to interpret these clues and recognise why oxygen alone does not determine the ending.

The -ide ending

For many ionic compounds, the first word names the positive ion, often a metal. The second word names the negative ion. In a compound made from two elements, the non-metal name commonly changes to end in -ide.

ElementsCompound name
sodium and chlorinesodium chloride
magnesium and oxygenmagnesium oxide
lithium and brominelithium bromide
calcium and sulfurcalcium sulfide

Chlorine is the element name; chloride is its negative ion name. Oxide contains oxygen, so an -ide ending does not mean that oxygen is absent.

The -ate ending

Names such as carbonate, nitrate and sulfate identify oxygen-containing negative group ions. The group contains oxygen together with another element.

CompoundElements presentNegative group contains
calcium carbonatecalcium, carbon, oxygencarbon and oxygen
potassium nitratepotassium, nitrogen, oxygennitrogen and oxygen
magnesium sulfatemagnesium, sulfur, oxygensulfur and oxygen

Compare magnesium sulfide with magnesium sulfate. Sulfide contains sulfur without oxygen; sulfate contains sulfur and oxygen in the group ion. The compounds therefore contain different elements despite their similar names. The ending is a clue to the named ion, not enough information by itself to deduce the complete compound formula.

Using the clues carefully

Worked comparison: sodium chloride contains sodium and chlorine only; chlorine is named chloride in the compound. Sodium carbonate contains sodium, carbon and oxygen because carbonate is an oxygen-containing group ion.

Do not reverse the -ate clue into “every ion containing oxygen ends in -ate”. Hydroxide, OHOH^-, contains oxygen and hydrogen but ends in -ide. Learn common names accurately: hydroxide, nitrate, carbonate and sulfate.