1.4 - Why atoms are electrically neutral
An atom has no overall electrical charge. Learn why this requires equal numbers of protons and electrons, and why their masses and the number of neutrons do not set that balance.
Why the charges cancel
Each proton has relative charge +1 and each electron has relative charge −1. Their charges have equal size and opposite signs. A neutral atom has zero overall charge, so it needs equal numbers of these particles.
For example, 8 protons contribute +8 and 8 electrons contribute −8. Their total is +8 + (−8) = 0. The particles remain present: it is their charges that cancel overall.
If proton and electron numbers are unequal, the particle has a net charge and is an ion.
Charge is not mass
Protons are much more massive than electrons, but each proton’s positive charge is still balanced by one electron’s negative charge. Equal mass is not required for charge balance.
Neutrons have relative charge 0. Adding or removing a neutron does not change the total electrical charge. An atom therefore does not need equal numbers of protons and neutrons to be neutral.