1.15 - Isotopes and the order of the periodic table

1.15 - Isotopes and the order of the periodic table

Relative atomic mass usually increases through the periodic table, but there are exceptions. You will use isotope abundance to explain why an element can have a larger average atomic mass than the element after it.

Why an average depends on abundance

Mendeleev expected increasing relative atomic mass to give the order of the elements. However, when this conflicted with chemical properties, he sometimes changed the mass order to keep similar elements together. Isotopes were not known at the time; they provide the modern explanation for the mass exceptions.

Relative atomic mass

The weighted mean mass of an atom of an element compared with one-twelfth of the mass of a carbon-12 atom.

Isotopes are atoms of the same element with the same proton number but different neutron numbers. Their masses differ. Relative abundance means the proportion of each isotope in a sample. A common isotope contributes more to the mean than a rare one.

For example, an element whose atoms are mostly the heavier of its isotopes has an average nearer that heavier isotope's mass. Simply saying “isotopes exist” misses the key link: their masses and relative abundances determine the weighted mean. There is no rule that these means must rise whenever proton number rises.

The tellurium and iodine exception

Tellurium comes before iodine in the periodic table, yet its relative atomic mass is greater.

ElementAtomic numberRelative atomic massNatural isotope pattern
Tellurium52127.60Several isotopes; heavy isotopes make large contributions
Iodine53126.90Almost entirely iodine-127

The greater contributions from heavy tellurium isotopes raise its weighted mean above iodine's. This does not change tellurium's proton number or chemical identity. Mendeleev placed the pair according to their chemical similarities; the modern table orders them by atomic number, 52 then 53.