39-41 - Resistivity and Charge-Carrier Model Core Practical
This lesson covers rows 39-41: using R = rho l / A, determining the electrical resistivity of a material in Core Practical 2, and using I = nqvA to explain why materials have such different resistivities. The thread through the lesson is simple: first measure how a real wire resists current, then strip away its length and thickness to find the material property, then explain that property using moving charge carriers.
Resistance Comes From Shape and Material
Imagine two wires made from the same metal. One is long and thin; the other is short and thick. They are not equally easy routes for charge. A longer wire gives charge carriers more material to move through, so its resistance is larger. A thicker wire gives more parallel paths through the cross-section, so its resistance is smaller.
That physical story is written as
R = rho l / A
where R is resistance in ohms, rho is electrical resistivity in ohm m, l is length in metres, and A is cross-sectional area in m^2.
Resistance belongs to a particular object. Resistivity belongs to the material, at a stated temperature. A short thick sample and a long thin sample of the same uniform material can have very different resistances, but they should give the same value of rho if measured well.
Rearrange the equation when the measurement is trying to find the material property:
rho = RA / l
For a circular wire,
A = pi r^2 = pi d^2 / 4
where d is the diameter. The easy mistake is to put the diameter straight into pi r^2. Radius is half the diameter, and all distances in the area calculation must be in metres.
Worked example: from a wire measurement to resistivity
A uniform wire has length 0.800 m and diameter 0.240 mm. Its resistance is measured as 5.6 ohm. Determine the resistivity of the wire material.
Decision point 1: the equation needs area, not diameter.
d = 0.240 mm = 2.40 x 10^-4 m
r = d / 2 = 1.20 x 10^-4 m
A = pi r^2 = pi(1.20 x 10^-4)^2 = 4.52 x 10^-8 m^2
Decision point 2: use rho = RA/l, because the material property is the unknown.
rho = (5.6)(4.52 x 10^-8) / 0.800
rho = 3.2 x 10^-7 ohm m
Decision point 3: check the unit. ohm x m^2 / m leaves ohm m, which is the unit of resistivity.
Misconception contrast: saying "this material has a resistance of 5.6 ohm" is not precise. That value belongs to this particular length and thickness. The material has a resistivity of about 3.2 x 10^-7 ohm m under these conditions.
Core Practical 2 Method
Core Practical 2 determines the electrical resistivity of a material, commonly using a long piece of constantan wire fixed along a metre ruler.
Each piece of apparatus has a job:
- the wire is the uniform sample whose resistivity is being found;
- the metre ruler gives the conducting length
l; - a crocodile clip fixes one end of the measured length;
- a moveable plug or contact touches the wire at different lengths;
- a digital multimeter on its lowest ohms range measures the resistance
R; - a micrometer screw gauge measures the small wire diameter accurately.
A clean method is:
- Fix the wire straight along a metre ruler and connect one end with a crocodile clip.
- Touch the moveable contact to the wire at about
0.10 mfrom the fixed end. - Record the length
lfrom the fixed end and the resistanceR. - Move the contact along the wire in equal steps, such as
0.10 m, recordingRandleach time. - Measure the wire diameter with a micrometer at several positions and in two perpendicular orientations where possible.
- Calculate the mean diameter and then the cross-sectional area.
- Plot
Ron the vertical axis againstlon the horizontal axis. - Use the gradient to calculate
rho.
Why graph it instead of using only one length? A graph uses all the readings and makes scatter visible. It also helps separate the length-dependent resistance of the wire from a roughly constant extra resistance caused by contacts or meter leads.
The graph should be straight for a uniform wire at constant temperature. From
R = rho l / A
compare with
y = mx + c
If R is on the vertical axis and l is on the horizontal axis, the gradient is
m = rho / A
so
rho = mA
The intercept may not be exactly zero. A non-zero intercept can come from contact resistance, meter-lead resistance or a small zero error. Those effects can shift the line up or down; the gradient is still the key measurement for the wire.
One practical caution is temperature. Resistivity depends on temperature, so the current through the wire should be small and the wire should not be left connected long enough to heat up. Heating changes the material while you are trying to measure it.
From Gradient to Resistivity
The graph route is a representation shift: the apparatus gives pairs of R and l; the graph turns those pairs into one gradient; the gradient turns into the material value rho.
Suppose a student measures the resistance of different lengths of a constantan wire. A best-fit line through the straight trend includes these two points:
Length l / m | Resistance R / ohm |
|---|---|
0.20 | 2.7 |
0.90 | 11.1 |
The micrometer gives a mean diameter of 0.230 mm.
Worked example: using the best-fit gradient
Decision point 1: use points on the best-fit line, not necessarily two raw data points.
gradient = Delta R / Delta l
gradient = (11.1 - 2.7) / (0.90 - 0.20)
gradient = 8.4 / 0.70 = 12.0 ohm m^-1
Decision point 2: calculate area from diameter in metres.
d = 0.230 mm = 2.30 x 10^-4 m
r = 1.15 x 10^-4 m
A = pi(1.15 x 10^-4)^2 = 4.15 x 10^-8 m^2
Decision point 3: connect the gradient back to the original equation.
Since gradient = rho/A,
rho = gradient x A
rho = 12.0 x 4.15 x 10^-8 = 4.98 x 10^-7 ohm m
So the measured resistivity is about
5.0 x 10^-7 ohm m
That is a "determine" style result: the value has been obtained through a quantitative method, not by recalling a number. Edexcel-style credit normally depends on showing the gradient route, using SI units for diameter and area, and giving the final unit.
A common wrong route is to use the intercept as the resistance of the wire. The gradient is what tells you how much extra resistance is added for each extra metre of wire. Resistivity is found from that length-dependent change.
Uncertainty and Evaluation
This practical is often limited by small measurements. The length may be measured to the nearest millimetre, but the diameter may be only a few tenths of a millimetre. A tiny absolute uncertainty in diameter can become a large percentage uncertainty in area.
Because
A = pi d^2 / 4
the percentage uncertainty in area is approximately twice the percentage uncertainty in diameter.
Worked example: combining the main percentage uncertainties
A student obtains
gradient = 12.0 +/- 0.5 ohm m^-1
and
d = 0.230 +/- 0.005 mm
Decision point 1: compare uncertainties as percentages.
Percentage uncertainty in gradient:
(0.5 / 12.0) x 100% = 4.2%
Percentage uncertainty in diameter:
(0.005 / 0.230) x 100% = 2.2%
Decision point 2: area depends on d^2, so double the diameter percentage uncertainty.
Percentage uncertainty in area:
2 x 2.2% = 4.4%
Decision point 3: rho = gradient x A, so add the percentage uncertainties.
Percentage uncertainty in rho:
4.2% + 4.4% = 8.6%
If rho = 5.0 x 10^-7 ohm m, the absolute uncertainty is about
0.086 x 5.0 x 10^-7 = 0.43 x 10^-7 ohm m
so a sensible report is
rho = (5.0 +/- 0.4) x 10^-7 ohm m
Method evaluation should use evidence, not a list of generic improvements:
- If the line has a non-zero intercept, discuss contact resistance, meter-lead resistance or zero error.
- If points are scattered, discuss random variation in contact pressure or reading instability.
- If the wire warms up, resistivity may change during the experiment.
- If diameter readings vary around the wire, the sample may not be perfectly uniform or circular.
- If diameter uncertainty dominates, take several micrometer readings in different places and orientations, check zero error, and calculate a mean.
For Edexcel evaluate or comment on prompts, a strong answer names the evidence and links it to the effect on rho. "Use better equipment" is too vague unless you say which measurement it improves and why.
The Charge-Carrier Model
The practical gives a macroscopic property: resistivity. Row 41 asks for the microscopic explanation using
I = nqvA
where:
| Symbol | Meaning | Unit |
|---|---|---|
I | current | ampere, A |
n | number of charge carriers per unit volume | m^-3 |
q | charge on each carrier | coulomb, C |
v | mean drift velocity of the carriers | m s^-1 |
A | cross-sectional area | m^2 |
The equation comes from a moving slice of charge. In a time Delta t, carriers with drift speed v move a distance v Delta t. The volume of wire that passes a cross-section is A v Delta t. If there are n carriers in each cubic metre, the number passing is n A v Delta t. Each has charge q, so
Delta Q = nqA v Delta t
and because I = Delta Q / Delta t,
I = nqvA
The drift velocity is slow. That does not mean the circuit response is slow. Individual electrons in a metal collide frequently and drift gradually, while the electric field change around the circuit is established very quickly.
Worked example: drift speed in a metal wire
A copper wire has diameter 1.0 mm and carries current 2.0 A. The number density of mobile electrons is 8.5 x 10^28 m^-3. Use the charge magnitude of an electron as 1.60 x 10^-19 C. Calculate the mean drift speed.
Decision point 1: use the magnitude of charge for the speed calculation; direction is a separate idea.
Decision point 2: calculate cross-sectional area from the radius.
r = 0.50 mm = 5.0 x 10^-4 m
A = pi(5.0 x 10^-4)^2 = 7.85 x 10^-7 m^2
Decision point 3: rearrange I = nqvA for v.
v = I / (nqA)
v = 2.0 / ((8.5 x 10^28)(1.60 x 10^-19)(7.85 x 10^-7))
v = 1.9 x 10^-4 m s^-1
That is less than a millimetre per second. A tempting but wrong idea is that electrons must rush round the whole circuit as soon as the switch is closed. The model says the current is large because the number of mobile carriers is enormous, not because each carrier has a large drift speed.
Why Resistivities Vary So Much
The two equations now meet.
R = rho l / A
connects resistance to the material and shape.
I = nqvA
connects current to the carriers moving through the cross-section.
For the same shape and the same potential difference, a material with a smaller current has a larger resistance. Since rho = RA/l, a larger resistance for the same length and area means a larger resistivity.
The charge-carrier model explains why the current can be very different:
nmay be large, as in a metal with many mobile electrons;nmay be very small, as in an insulator with very few mobile charge carriers;- the drift speed
vfor a given electric field may be small if carriers collide often or are not very mobile; - the charge
qis fixed for electrons, but in other conducting materials, such as electrolytes, the mobile carriers may be ions with different charges.
So a low-resistivity material is not "a material where charges feel no resistance". It is a material where, for a given electric field and sample shape, enough mobile charge passes each second to give a large current. A high-resistivity material gives a much smaller current because there are fewer mobile carriers, less mobile carriers, or both.
This also explains why resistivity is temperature dependent. In a metal, higher temperature usually means stronger lattice vibrations and more collisions, so the drift speed for a given electric field is reduced. In a semiconductor, heating can increase the number of mobile carriers, so the effect can be different. The detailed temperature models sit beyond this row, but the row 41 idea is the same: carrier number and carrier motion matter.
For Edexcel explain questions, do not stop at "there are more charge carriers." Link the chain:
larger n or v -> larger I for the same A -> smaller R for the same potential difference -> smaller rho for the same l and A
or the reverse chain for a high-resistivity material.